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Chiral Lanthanide Complexes with l- and d-Alanine: An X-ray and Vibrational Circular Dichroism Study

A whole series of [Ln(H(2)O)(4)(Ala)(2)](2)(6+) dimeric cationic lanthanide complexes with both l- and d-alanine enantiomers was synthesized. The single-crystal X-ray diffraction at 100 and 292 K shows the formation of two types of dimers (I and II) in crystals. Between the dimer centers, the alanin...

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Detalhes bibliográficos
Publicado no:Molecules
Main Authors: Lyczko, Krzysztof, Rode, Joanna E., Dobrowolski, Jan Cz.
Formato: Artigo
Idioma:Inglês
Publicado em: MDPI 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7357152/
https://ncbi.nlm.nih.gov/pubmed/32545530
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules25122729
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