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Photoredox-catalyzed silyldifluoromethylation of silyl enol ethers

A method for the light-mediated fluoroalkylation of silyl enol ethers with (bromodifluoromethyl)trimethylsilane followed by a reduction of the primary products with sodium borohydride is described. An 18 W, 375 nm LED was used as the light source. The reaction is performed in the presence of a gold...

Disgrifiad llawn

Wedi'i Gadw mewn:
Manylion Llyfryddiaeth
Cyhoeddwyd yn:Beilstein J Org Chem
Prif Awduron: Supranovich, Vyacheslav I, Levin, Vitalij V, Dilman, Alexander D
Fformat: Artigo
Iaith:Inglês
Cyhoeddwyd: Beilstein-Institut 2020
Pynciau:
Mynediad Ar-lein:https://ncbi.nlm.nih.gov/pmc/articles/PMC7356207/
https://ncbi.nlm.nih.gov/pubmed/32704320
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.16.126
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