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Gold-catalyzed alkylation of silyl enol ethers with ortho-alkynylbenzoic acid esters

Unprecedented alkylation of silyl enol ethers has been developed by the use of ortho-alkynylbenzoic acid alkyl esters as alkylating agents in the presence of a gold catalyst. The reaction probably proceeds through the gold-induced in situ construction of leaving groups and subsequent nucleophilic at...

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Detalhes bibliográficos
Main Authors: Aikawa, Haruo, Kaneko, Tetsuro, Asao, Naoki, Yamamoto, Yoshinori
Formato: Artigo
Idioma:Inglês
Publicado em: Beilstein-Institut 2011
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3107469/
https://ncbi.nlm.nih.gov/pubmed/21647329
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.7.76
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