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FLP‐Catalyzed Transfer Hydrogenation of Silyl Enol Ethers
Herein we report the first catalytic transfer hydrogenation of silyl enol ethers. This metal free approach employs tris(pentafluorophenyl)borane and 2,2,6,6‐tetramethylpiperidine (TMP) as a commercially available FLP catalyst system and naturally occurring γ‐terpinene as a dihydrogen surrogate. A va...
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| Publié dans: | Angew Chem Int Ed Engl |
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| Auteurs principaux: | , , , |
| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
John Wiley and Sons Inc.
2018
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6207922/ https://ncbi.nlm.nih.gov/pubmed/30106498 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201808800 |
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