FLP‐Catalyzed Transfer Hydrogenation of Silyl Enol Ethers

Herein we report the first catalytic transfer hydrogenation of silyl enol ethers. This metal free approach employs tris(pentafluorophenyl)borane and 2,2,6,6‐tetramethylpiperidine (TMP) as a commercially available FLP catalyst system and naturally occurring γ‐terpinene as a dihydrogen surrogate. A va...

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Detaylı Bibliyografya
Yayımlandı:Angew Chem Int Ed Engl
Asıl Yazarlar: Khan, Imtiaz, Reed‐Berendt, Benjamin G., Melen, Rebecca L., Morrill, Louis C.
Materyal Türü: Artigo
Dil:Inglês
Baskı/Yayın Bilgisi: John Wiley and Sons Inc. 2018
Konular:
Communications
Online Erişim:https://ncbi.nlm.nih.gov/pmc/articles/PMC6207922/
https://ncbi.nlm.nih.gov/pubmed/30106498
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201808800
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