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Catalytic [5 + 1]-Cycloadditions of Vinylcyclopropanes and Vinylidenes
Polysubstituted cyclohexenes bearing 1,3 (meta) substitution patterns are challenging to access using the Diels–Alder reaction (the ortho–para rule). Here, we report a cobalt-catalyzed reductive [5 + 1]-cycloaddition between a vinylcyclopropane and a vinylidene to provide methylenecyclohexenes beari...
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| Publicado no: | J Am Chem Soc |
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| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2020
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7334882/ https://ncbi.nlm.nih.gov/pubmed/32083863 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.0c00356 |
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