Enantioselective Hydroxylation of Benzylic C(sp(3))–H Bonds by an Artificial Iron Hydroxylase Based on the Biotin–Streptavidin Technology

[Image: see text] The selective hydroxylation of C–H bonds is of great interest to the synthetic community. Both homogeneous catalysts and enzymes offer complementary means to tackle this challenge. Herein, we show that biotinylated Fe(TAML)-complexes (TAML = Tetra Amido Macrocyclic Ligand) can be u...

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Publicat a:J Am Chem Soc
Autors principals: Serrano-Plana, Joan, Rumo, Corentin, Rebelein, Johannes G., Peterson, Ryan L., Barnet, Maxime, Ward, Thomas R.
Format: Artigo
Idioma:Inglês
Publicat: American Chemical Society 2020
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC7332155/
https://ncbi.nlm.nih.gov/pubmed/32450689
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.0c02788
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