Enantioselective Hydroxylation of Benzylic C(sp(3))–H Bonds by an Artificial Iron Hydroxylase Based on the Biotin–Streptavidin Technology

[Image: see text] The selective hydroxylation of C–H bonds is of great interest to the synthetic community. Both homogeneous catalysts and enzymes offer complementary means to tackle this challenge. Herein, we show that biotinylated Fe(TAML)-complexes (TAML = Tetra Amido Macrocyclic Ligand) can be u...

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Detalles Bibliográficos
Publicado en:J Am Chem Soc
Autores principales: Serrano-Plana, Joan, Rumo, Corentin, Rebelein, Johannes G., Peterson, Ryan L., Barnet, Maxime, Ward, Thomas R.
Formato: Artigo
Lenguaje:Inglês
Publicado: American Chemical Society 2020
Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC7332155/
https://ncbi.nlm.nih.gov/pubmed/32450689
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.0c02788
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