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Enantioselective Hydroxylation of Benzylic C(sp(3))–H Bonds by an Artificial Iron Hydroxylase Based on the Biotin–Streptavidin Technology
[Image: see text] The selective hydroxylation of C–H bonds is of great interest to the synthetic community. Both homogeneous catalysts and enzymes offer complementary means to tackle this challenge. Herein, we show that biotinylated Fe(TAML)-complexes (TAML = Tetra Amido Macrocyclic Ligand) can be u...
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| Publicado no: | J Am Chem Soc |
|---|---|
| Main Authors: | , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
American Chemical
Society
2020
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| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7332155/ https://ncbi.nlm.nih.gov/pubmed/32450689 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.0c02788 |
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