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Studies on the Stability and Stabilization of trans-Cyclooctenes through Radical Inhibition and Silver (I) Metal Complexation
Conformationally strained trans-cyclooctenes (TCOs) engage in bioorthogonal reactions with tetrazines with second order rate constants that can exceed 10(6) M(−1)s(−1). The goal of this study was to provide insight into the stability of TCO reagents and to develop methods for stabilizing TCO reagent...
Kaydedildi:
| Yayımlandı: | Tetrahedron |
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| Asıl Yazarlar: | , , , , , , , , |
| Materyal Türü: | Artigo |
| Dil: | Inglês |
| Baskı/Yayın Bilgisi: |
2019
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| Konular: | |
| Online Erişim: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7328862/ https://ncbi.nlm.nih.gov/pubmed/32612312 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2019.05.038 |
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