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Acid‐Catalyzed Rearrangements of 3‐Aryloxirane‐2‐Carboxamides: Novel DFT Mechanistic Insights

Efficient synthesis of 3‐arylquinolin‐2(1H)‐ones and N‐(2‐carboxyaryl)‐oxalamides from protic acid‐catalyzed rearrangements of 3‐aryloxirane‐2‐carboxamides was achieved recently but not well understood. In contrast to the classical Meinwald rearrangement, extensive DFT calculations reveal that the p...

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Detalhes bibliográficos
Publicado no:ChemistryOpen
Main Authors: Qu, Zheng‐Wang, Zhu, Hui, Katsyuba, Sergey A., Mamedova, Vera L., Mamedov, Vakhid A., Grimme, Stefan
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7327482/
https://ncbi.nlm.nih.gov/pubmed/32626644
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/open.202000110
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