Mechanistic Insights of BHT-Mg-Catalyzed Ethylene Phosphate’s Coordination Ring-Opening Polymerization: DFT Modeling and Experimental Data

Poly(ethylene phosphates) are promising polymers for use in biomedical applications. Catalytic ring-opening polymerization (ROP) of cyclic ethylene phosphate monomers (CEPMs) is the most effective approach for obtaining these polymers. The mechanism of coordination ROP of CEPMs remains unclear. We r...

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Vydáno v:Polymers (Basel)
Hlavní autoři: Nifant’ev, Ilya, Shlyakhtin, Andrey, Kosarev, Maxim, Karchevsky, Stanislav, Ivchenko, Pavel
Médium: Artigo
Jazyk:Inglês
Vydáno: MDPI 2018
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Article
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC6403938/
https://ncbi.nlm.nih.gov/pubmed/30961030
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/polym10101105
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