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Differences between the elimination of early and late transition metals: DFT mechanistic insights into the titanium-catalyzed synthesis of pyrroles from alkynes and diazenes
Early transition metals (TMs), such as titanium, generally resist undergoing reductive elimination to form C–X bonds due to their weak electronegativity. By analyzing the mechanism of the titanium-catalyzed synthesis of pyrroles from alkynes and diazenes, the present study revealed that titanium is...
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| Publicado no: | Chem Sci |
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| Main Authors: | , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Royal Society of Chemistry
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5369339/ https://ncbi.nlm.nih.gov/pubmed/28451348 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6sc04456e |
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