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Differences between the elimination of early and late transition metals: DFT mechanistic insights into the titanium-catalyzed synthesis of pyrroles from alkynes and diazenes

Early transition metals (TMs), such as titanium, generally resist undergoing reductive elimination to form C–X bonds due to their weak electronegativity. By analyzing the mechanism of the titanium-catalyzed synthesis of pyrroles from alkynes and diazenes, the present study revealed that titanium is...

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Bibliografske podrobnosti
izdano v:Chem Sci
Main Authors: Guo, Jiandong, Deng, Xi, Song, Chunyu, Lu, Yu, Qu, Shuanglin, Dang, Yanfeng, Wang, Zhi-Xiang
Format: Artigo
Jezik:Inglês
Izdano: Royal Society of Chemistry 2017
Teme:
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC5369339/
https://ncbi.nlm.nih.gov/pubmed/28451348
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6sc04456e
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