Cobalt-catalyzed highly enantioselective hydrogenation of α,β-unsaturated carboxylic acids

Asymmetric hydrogenation of α,β-unsaturated acids catalyzed by noble metals has been well established, whereas, the asymmetric hydrogenation with earth-abundant-metal was rarely reported. Here, we describe a cobalt-catalyzed asymmetric hydrogenation of α,β-unsaturated carboxylic acids. By using chir...

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Veröffentlicht in:Nat Commun
Hauptverfasser: Du, Xiaoyong, Xiao, Ye, Huang, Jia-Ming, Zhang, Yao, Duan, Ya-Nan, Wang, Heng, Shi, Chuan, Chen, Gen-Qiang, Zhang, Xumu
Format: Artigo
Sprache:Inglês
Veröffentlicht: Nature Publishing Group UK 2020
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Article
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC7319995/
https://ncbi.nlm.nih.gov/pubmed/32591536
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41467-020-17057-z
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