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Cobalt-Catalyzed Intramolecular Silylperoxidation of Unsaturated Diisopropylsilyl Ethers

A cobalt-catalyzed intramolecular silylperoxidation reaction was developed that allows for the conversion of unsaturated diisopropylsilyl ethers to 3-sila-1,2,4-trioxepanes. Reduction of the peroxide unit of the 3-sila-1,2,4-trioxepane yields six-membered ring diisopropylsilylene acetals.

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Bibliographic Details
Published in:J Org Chem
Main Authors: Oswald, Jonathan P., Woerpel, K. A.
Format: Artigo
Language:Inglês
Published: 2019
Subjects:
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC7189782/
https://ncbi.nlm.nih.gov/pubmed/31046281
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.9b00642
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