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Ni-Catalyzed Intramolecular C–O Bond Formation: Synthesis of Cyclic Enol Ethers

An efficient and exceptionally mild intramolecular nickel-catalyzed carbon–oxygen bond-forming reaction between vinyl halides and primary, secondary, and tertiary alcohols has been achieved. Zinc powder was found to be an essential additive for obtaining high catalyst turnover and yields. This opera...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Han, Seo-Jung, Doi, Ryohei, Stoltz, Brian M.
Formato: Artigo
Idioma:Inglês
Publicado em: 2016
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4985346/
https://ncbi.nlm.nih.gov/pubmed/27159831
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201601991
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