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Stereoselective Synthesis of Cyclic Ethers via the Palladium-Catalyzed Intramolecular Addition of Alcohols to Phosphono Allylic Carbonates
[Image: see text] Cross metathesis of the acrolein derived phosphono allylic carbonate and hydroxy alkenes using second generation Grubbs catalyst and copper (I) iodide gave the substituted phosphonates in good yield. Stereospecific palladium (0)-catalyzed cyclization gave tetrahydrofuran and tetrah...
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| Glavni autori: | , , |
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| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
2009
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| Teme: | |
| Online pristup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2717013/ https://ncbi.nlm.nih.gov/pubmed/19586068 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol900980s |
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