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Heterogeneous Olefin Hydrogenation Enabled by a Highly‐Reduced Nickel(−II) Catalyst Precursor
The hydrogenation of olefins, styrenes, enoates, imines, and sterically hindered tri‐substituted olefins was accomplished using the pre‐catalyst dilithiumbis(cycloocta‐1,5‐diene)nickelate(−II) (1). The mild conditions tolerate hydroxyl, halide, ester, and lactone functionalities. Mechanistic studies...
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| Udgivet i: | Chemistry |
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| Main Authors: | , , , , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
John Wiley and Sons Inc.
2020
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7318650/ https://ncbi.nlm.nih.gov/pubmed/32034810 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201905537 |
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