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Dipyrrolyl Precursors to Bisalkoxide Molybdenum Olefin Metathesis Catalysts
Addition of two equivalents of lithium pyrrolide to Mo(NR)(CHCMe(2)R')(OTf)(2)(DME) (OTf = OSO(2)CF(3); R = 2,6-i-Pr(2)C(6)H(3), 1-adamantyl, or 2,6-Br(2)-4-MeC(6)H(2); R' = Me or Ph) produces Mo(NR)(CHCMe(2)R')(NC(4)H(4))(2) complexes in good yield. All compounds can be recrystallize...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
2006
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2528246/ https://ncbi.nlm.nih.gov/pubmed/17165793 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja0665904 |
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