Diphenylamido Precursors to Bisalkoxide Molybdenum Olefin Metathesis Catalysts

We have found that Mo(NAr)(CHR′)(NPh(2))(2) (R′ = t-Bu or CMe(2)Ph) and Mo(NAr′)(CHCMe(2)Ph)(NPh(2))(2) (Ar = 2,6-i-Pr(2)C(6)H(3); Ar′ = 2,6-Me(2)C(6)H(3)) can be prepared through addition of two equivalents of LiNPh(2) to Mo(NR″)(CHR′)(OTf)(2)(dme) species (R″ = Ar or Ar′ dme = 1,2-dimethoxyethane)...

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Main Authors: Sinha, Amritanshu, Schrock, Richard R., Müller, Peter, Hoveyda, Amir H.
Formato: Artigo
Idioma:Inglês
Publicado: 2006
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Article
Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC2585777/
https://ncbi.nlm.nih.gov/pubmed/19030118
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/om060430j
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