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Diphenylamido Precursors to Bisalkoxide Molybdenum Olefin Metathesis Catalysts
We have found that Mo(NAr)(CHR′)(NPh(2))(2) (R′ = t-Bu or CMe(2)Ph) and Mo(NAr′)(CHCMe(2)Ph)(NPh(2))(2) (Ar = 2,6-i-Pr(2)C(6)H(3); Ar′ = 2,6-Me(2)C(6)H(3)) can be prepared through addition of two equivalents of LiNPh(2) to Mo(NR″)(CHR′)(OTf)(2)(dme) species (R″ = Ar or Ar′ dme = 1,2-dimethoxyethane)...
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| Auteurs principaux: | , , , |
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| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
2006
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2585777/ https://ncbi.nlm.nih.gov/pubmed/19030118 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/om060430j |
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