Heterogeneous Olefin Hydrogenation Enabled by a Highly‐Reduced Nickel(−II) Catalyst Precursor

The hydrogenation of olefins, styrenes, enoates, imines, and sterically hindered tri‐substituted olefins was accomplished using the pre‐catalyst dilithiumbis(cycloocta‐1,5‐diene)nickelate(−II) (1). The mild conditions tolerate hydroxyl, halide, ester, and lactone functionalities. Mechanistic studies...

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Bibliographic Details
Published in:Chemistry
Main Authors: Maier, Thomas M., Sandl, Sebastian, Melzl, Peter, Zweck, Josef, Jacobi von Wangelin, Axel, Wolf, Robert
Format: Artigo
Language:Inglês
Published: John Wiley and Sons Inc. 2020
Subjects:
Communications
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC7318650/
https://ncbi.nlm.nih.gov/pubmed/32034810
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201905537
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