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Unusual Racemization of Tertiary P‐Chiral Ferrocenyl Phosphines
Tertiary phosphines are generally known to withstand inversion under moderate conditions. In this work, a remarkable racemization process of three P‐chiral ferrocenyl phosphines is reported. Subjected to conventional column chromatography as highly enantioenriched compounds, they greatly experienced...
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| Veröffentlicht in: | Chemistry |
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| Hauptverfasser: | , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
John Wiley and Sons Inc.
2020
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7317868/ https://ncbi.nlm.nih.gov/pubmed/32048370 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202000218 |
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