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Tricoordinate Coinage Metal Complexes with a Redox‐Active Tris‐(Ferrocenyl)triazine Backbone Feature Triazine–Metal Interactions

2,4,6‐Tris(1‐diphenylphosphanyl‐1’‐ferrocenylene)‐1,3,5‐triazine (1) coordinates all three coinage metal(I) ions in a 1:1 tridentate coordination mode. The C(3)‐symmetric coordination in both solid state and solution is stabilised by an uncommon cation–π interaction between the triazine core and the...

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Détails bibliographiques
Publié dans:Chemistry
Auteurs principaux: Straube, Axel, Coburger, Peter, Ringenberg, Mark R., Hey‐Hawkins, Evamarie
Format: Artigo
Langue:Inglês
Publié: John Wiley and Sons Inc. 2020
Sujets:
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC7317378/
https://ncbi.nlm.nih.gov/pubmed/32022973
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202000226
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