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Unusual Racemization of Tertiary P‐Chiral Ferrocenyl Phosphines

Tertiary phosphines are generally known to withstand inversion under moderate conditions. In this work, a remarkable racemization process of three P‐chiral ferrocenyl phosphines is reported. Subjected to conventional column chromatography as highly enantioenriched compounds, they greatly experienced...

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Bibliografski detalji
Izdano u:Chemistry
Glavni autori: Popp, John, Hanf, Schirin, Hey‐Hawkins, Evamarie
Format: Artigo
Jezik:Inglês
Izdano: John Wiley and Sons Inc. 2020
Teme:
Online pristup:https://ncbi.nlm.nih.gov/pmc/articles/PMC7317868/
https://ncbi.nlm.nih.gov/pubmed/32048370
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202000218
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