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Importance of Methane Chemical Potential for Its Conversion to Methanol on Cu‐Exchanged Mordenite
Copper‐oxo clusters exchanged in zeolite mordenite are active in the stoichiometric conversion of methane to methanol at low temperatures. Here, we show an unprecedented methanol yield per Cu of 0.6, with a 90–95 % selectivity, on a MOR solely containing [Cu(3)(μ‐O)(3)](2+) active sites. DFT calcula...
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| Pubblicato in: | Chemistry |
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| Autori principali: | , , , , , , , , , , , , , |
| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
John Wiley and Sons Inc.
2020
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7317825/ https://ncbi.nlm.nih.gov/pubmed/32092206 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202000772 |
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