Importance of Methane Chemical Potential for Its Conversion to Methanol on Cu‐Exchanged Mordenite

Copper‐oxo clusters exchanged in zeolite mordenite are active in the stoichiometric conversion of methane to methanol at low temperatures. Here, we show an unprecedented methanol yield per Cu of 0.6, with a 90–95 % selectivity, on a MOR solely containing [Cu(3)(μ‐O)(3)](2+) active sites. DFT calcula...

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Vydáno v:Chemistry
Hlavní autoři: Zheng, Jian, Lee, Insu, Khramenkova, Elena, Wang, Meng, Peng, Bo, Gutiérrez, Oliver Y., Fulton, John L., Camaioni, Donald M., Khare, Rachit, Jentys, Andreas, Haller, Gary L., Pidko, Evgeny A., Sanchez‐Sanchez, Maricruz, Lercher, Johannes A.
Médium: Artigo
Jazyk:Inglês
Vydáno: John Wiley and Sons Inc. 2020
Témata:
Communications
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC7317825/
https://ncbi.nlm.nih.gov/pubmed/32092206
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202000772
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