Importance of Methane Chemical Potential for Its Conversion to Methanol on Cu‐Exchanged Mordenite

Copper‐oxo clusters exchanged in zeolite mordenite are active in the stoichiometric conversion of methane to methanol at low temperatures. Here, we show an unprecedented methanol yield per Cu of 0.6, with a 90–95 % selectivity, on a MOR solely containing [Cu(3)(μ‐O)(3)](2+) active sites. DFT calcula...

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Detalles Bibliográficos
Publicado en:Chemistry
Main Authors: Zheng, Jian, Lee, Insu, Khramenkova, Elena, Wang, Meng, Peng, Bo, Gutiérrez, Oliver Y., Fulton, John L., Camaioni, Donald M., Khare, Rachit, Jentys, Andreas, Haller, Gary L., Pidko, Evgeny A., Sanchez‐Sanchez, Maricruz, Lercher, Johannes A.
Formato: Artigo
Idioma:Inglês
Publicado: John Wiley and Sons Inc. 2020
Assuntos:
Communications
Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC7317825/
https://ncbi.nlm.nih.gov/pubmed/32092206
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202000772
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