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Importance of Methane Chemical Potential for Its Conversion to Methanol on Cu‐Exchanged Mordenite

Copper‐oxo clusters exchanged in zeolite mordenite are active in the stoichiometric conversion of methane to methanol at low temperatures. Here, we show an unprecedented methanol yield per Cu of 0.6, with a 90–95 % selectivity, on a MOR solely containing [Cu(3)(μ‐O)(3)](2+) active sites. DFT calcula...

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Bibliografiske detaljer
Udgivet i:Chemistry
Main Authors: Zheng, Jian, Lee, Insu, Khramenkova, Elena, Wang, Meng, Peng, Bo, Gutiérrez, Oliver Y., Fulton, John L., Camaioni, Donald M., Khare, Rachit, Jentys, Andreas, Haller, Gary L., Pidko, Evgeny A., Sanchez‐Sanchez, Maricruz, Lercher, Johannes A.
Format: Artigo
Sprog:Inglês
Udgivet: John Wiley and Sons Inc. 2020
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC7317825/
https://ncbi.nlm.nih.gov/pubmed/32092206
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202000772
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