Importance of Methane Chemical Potential for Its Conversion to Methanol on Cu‐Exchanged Mordenite

Copper‐oxo clusters exchanged in zeolite mordenite are active in the stoichiometric conversion of methane to methanol at low temperatures. Here, we show an unprecedented methanol yield per Cu of 0.6, with a 90–95 % selectivity, on a MOR solely containing [Cu(3)(μ‐O)(3)](2+) active sites. DFT calcula...

Full beskrivning

Sparad:
Bibliografiska uppgifter
I publikationen:Chemistry
Huvudupphovsmän: Zheng, Jian, Lee, Insu, Khramenkova, Elena, Wang, Meng, Peng, Bo, Gutiérrez, Oliver Y., Fulton, John L., Camaioni, Donald M., Khare, Rachit, Jentys, Andreas, Haller, Gary L., Pidko, Evgeny A., Sanchez‐Sanchez, Maricruz, Lercher, Johannes A.
Materialtyp: Artigo
Språk:Inglês
Publicerad: John Wiley and Sons Inc. 2020
Ämnen:
Communications
Länkar:https://ncbi.nlm.nih.gov/pmc/articles/PMC7317825/
https://ncbi.nlm.nih.gov/pubmed/32092206
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202000772
Taggar: Lägg till en tagg
Inga taggar, Lägg till första taggen!

Liknande verk