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Ferrocenyl-substituted tetrahydrothiophenes via formal [3 + 2]-cycloaddition reactions of ferrocenyl thioketones with donor–acceptor cyclopropanes

Ferrocenyl thioketones reacted with donor–acceptor cyclopropanes in dichloromethane at room temperature in the presence of catalytic amounts of Sc(OTf)(3) yielding tetrahydrothiophene derivatives, products of formal [3 + 2]-cycloaddition reactions, in moderate to high yields. In all studied cases, d...

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Bibliografiska uppgifter
I publikationen:Beilstein J Org Chem
Huvudupphovsmän: Mlostoń, Grzegorz, Kowalczyk, Mateusz, Augustin, André U, Jones, Peter G, Werz, Daniel B
Materialtyp: Artigo
Språk:Inglês
Publicerad: Beilstein-Institut 2020
Ämnen:
Länkar:https://ncbi.nlm.nih.gov/pmc/articles/PMC7296194/
https://ncbi.nlm.nih.gov/pubmed/32566031
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.16.109
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