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Ferrocenyl-substituted tetrahydrothiophenes via formal [3 + 2]-cycloaddition reactions of ferrocenyl thioketones with donor–acceptor cyclopropanes

Ferrocenyl thioketones reacted with donor–acceptor cyclopropanes in dichloromethane at room temperature in the presence of catalytic amounts of Sc(OTf)(3) yielding tetrahydrothiophene derivatives, products of formal [3 + 2]-cycloaddition reactions, in moderate to high yields. In all studied cases, d...

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Bibliographische Detailangaben
Veröffentlicht in:Beilstein J Org Chem
Hauptverfasser: Mlostoń, Grzegorz, Kowalczyk, Mateusz, Augustin, André U, Jones, Peter G, Werz, Daniel B
Format: Artigo
Sprache:Inglês
Veröffentlicht: Beilstein-Institut 2020
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Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC7296194/
https://ncbi.nlm.nih.gov/pubmed/32566031
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.16.109
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