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Ferrocenyl-substituted tetrahydrothiophenes via formal [3 + 2]-cycloaddition reactions of ferrocenyl thioketones with donor–acceptor cyclopropanes

Ferrocenyl thioketones reacted with donor–acceptor cyclopropanes in dichloromethane at room temperature in the presence of catalytic amounts of Sc(OTf)(3) yielding tetrahydrothiophene derivatives, products of formal [3 + 2]-cycloaddition reactions, in moderate to high yields. In all studied cases, d...

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Detalles Bibliográficos
Publicado en:Beilstein J Org Chem
Main Authors: Mlostoń, Grzegorz, Kowalczyk, Mateusz, Augustin, André U, Jones, Peter G, Werz, Daniel B
Formato: Artigo
Idioma:Inglês
Publicado: Beilstein-Institut 2020
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Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC7296194/
https://ncbi.nlm.nih.gov/pubmed/32566031
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.16.109
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