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Ferrocenyl-substituted tetrahydrothiophenes via formal [3 + 2]-cycloaddition reactions of ferrocenyl thioketones with donor–acceptor cyclopropanes

Ferrocenyl thioketones reacted with donor–acceptor cyclopropanes in dichloromethane at room temperature in the presence of catalytic amounts of Sc(OTf)(3) yielding tetrahydrothiophene derivatives, products of formal [3 + 2]-cycloaddition reactions, in moderate to high yields. In all studied cases, d...

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Dades bibliogràfiques
Publicat a:Beilstein J Org Chem
Autors principals: Mlostoń, Grzegorz, Kowalczyk, Mateusz, Augustin, André U, Jones, Peter G, Werz, Daniel B
Format: Artigo
Idioma:Inglês
Publicat: Beilstein-Institut 2020
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC7296194/
https://ncbi.nlm.nih.gov/pubmed/32566031
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.16.109
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