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Highly Enantioselective, Hydrogen-Bond-Donor Catalyzed Additions to Oxetanes
A precisely designed chiral squaramide derivative is shown to promote the highly enantioselective addition of trimethylsilyl bromide (TMSBr) to a broad variety of 3-substituted and 3,3-disubstituted oxetanes. The reaction provides direct and general access to synthetically valuable 1,3-bromohydrin b...
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| Publicado no: | J Am Chem Soc |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2020
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7293824/ https://ncbi.nlm.nih.gov/pubmed/32364378 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.0c03991 |
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