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Synthesis of Quaternary Carbon Stereogenic Centers by Diastereoselective Conjugate Addition of Boron-Stabilized Allylic Nucleophiles to Enones

A method for the site-selective and diastereoselective conjugate addition of boron-stabilized allylic nucleophiles to α,β-unsaturated ketones is disclosed. Transformations involve easily prepared γ,γ-disubstituted allyldiboron reagents and proceed in the presence of a fluoride activator at 80°C. Rea...

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Bibliografiske detaljer
Udgivet i:J Am Chem Soc
Main Authors: Liang, Michael Z., Meek, Simon J.
Format: Artigo
Sprog:Inglês
Udgivet: 2020
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC7289652/
https://ncbi.nlm.nih.gov/pubmed/32408746
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.0c03900
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