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De Novo Synthesis of the DEF-Ring Stereotriad Core of the Veratrum Alkaloids
The synthesis of the stereotriad core in the eastern portion of the Veratrum alkaloids jervine (1), cyclopamine (2), and veratramine (3) is reported. Starting from a known β-methyltyrosine derivative (8), the route utilizes a diastereoselective substrate-controlled 1,2-reduction to establish the ste...
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| Publicado en: | J Org Chem |
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| Autores principales: | , , |
| Formato: | Artigo |
| Lenguaje: | Inglês |
| Publicado: |
2020
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| Materias: | |
| Acceso en línea: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7246867/ https://ncbi.nlm.nih.gov/pubmed/32352768 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.0c00685 |
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