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Construction of the Tricyclic A-B-C Core of the Veratrum Alkaloids

[Image: see text] Organocatalyzed enantioselective allylation of 2-iodocyclohexenone followed by methylation and oxy-Cope rearrangement delivered enantiomerically-enriched 2-methyl 3-allyl cyclohexanone, that engaged in acid-catalyzed Robinson annulation to give the bicyclic enone. Subsequent elabor...

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Publicado en:J Org Chem
Main Authors: Taber, Douglass F., Berry, James F.
Formato: Artigo
Idioma:Inglês
Publicado: 2013
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Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC4255024/
https://ncbi.nlm.nih.gov/pubmed/23859604
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo401158d
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