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Construction of the Tricyclic A-B-C Core of the Veratrum Alkaloids
[Image: see text] Organocatalyzed enantioselective allylation of 2-iodocyclohexenone followed by methylation and oxy-Cope rearrangement delivered enantiomerically-enriched 2-methyl 3-allyl cyclohexanone, that engaged in acid-catalyzed Robinson annulation to give the bicyclic enone. Subsequent elabor...
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| Pubblicato in: | J Org Chem |
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| Autori principali: | , |
| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
2013
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4255024/ https://ncbi.nlm.nih.gov/pubmed/23859604 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo401158d |
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