Activation of allylic esters in an intramolecular vinylogous kinetic resolution reaction with synergistic magnesium catalysts

Kinetic resolution (KR) of racemic starting materials is a powerful and practical alternative to prepare valuable enantiomerically enriched compounds. A magnesium-catalyzed kinetic resolution based on a designed intramolecular vinylogous Michael reaction is disclosed. Here we show a synergistic cata...

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Publicat a:Nat Commun
Autors principals: Li, Dan, Yang, Yuling, Zhang, Minmin, Wang, Linqing, Xu, Yingfan, Yang, Dongxu, Wang, Rui
Format: Artigo
Idioma:Inglês
Publicat: Nature Publishing Group UK 2020
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Article
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC7244749/
https://ncbi.nlm.nih.gov/pubmed/32444612
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41467-020-16486-0
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