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Kinetic Studies that Evaluate the Solvolytic Mechanisms of Allyl and Vinyl Chloroformate Esters

At 25.0 °C the specific rates of solvolysis for allyl and vinyl chloroformates have been determined in a wide mix of pure and aqueous organic mixtures. In all the solvents studied, vinyl chloroformate was found to react significantly faster than allyl chloroformate. Multiple correlation analyses of...

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Autors principals: D’Souza, Malcolm J., Givens, Aaron F., Lorchak, Peter A., Greenwood, Abigail E., Gottschall, Stacey L., Carter, Shannon E., Kevill, Dennis N.
Format: Artigo
Idioma:Inglês
Publicat: Molecular Diversity Preservation International (MDPI) 2013
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC3645686/
https://ncbi.nlm.nih.gov/pubmed/23549265
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/ijms14047286
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