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Photochemically-mediated nickel-catalyzed synthesis of N-(hetero)aryl sulfamides

A general method for the N-arylation of sulfamides with aryl bromides is described. The protocol leverages a dual-catalytic system, with [Ir(ppy)(2)(dtbbpy)]PF(6) as a photosensitizer, NiBr(2)•glyme as a precatalyst, and DBU as a base, and proceeds at room temperature under visible light irradiation...

Deskribapen osoa

Gorde:
Xehetasun bibliografikoak
Argitaratua izan da:J Org Chem
Egile Nagusiak: Simons, R. Thomas, Scott, Georgia E., Kanegusuku, Anastasia G., Roizen, Jennifer L.
Formatua: Artigo
Hizkuntza:Inglês
Argitaratua: 2020
Gaiak:
Sarrera elektronikoa:https://ncbi.nlm.nih.gov/pmc/articles/PMC7241444/
https://ncbi.nlm.nih.gov/pubmed/32312047
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.0c00139
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