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Difluoromethylation of (hetero)aryl chlorides with chlorodifluoromethane catalyzed by nickel
Relatively low reactivity hinders using chlorodifluoromethane (ClCF(2)H) for general difluoromethylation with organic molecules, despite its availability as an inexpensive industrial chemical. To date, transformations of ClCF(2)H are very limited and most of them involve difluorocarbene intermediate...
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| Publicado no: | Nat Commun |
|---|---|
| Main Authors: | , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Nature Publishing Group UK
2018
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5862906/ https://ncbi.nlm.nih.gov/pubmed/29563528 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41467-018-03532-1 |
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