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Photochemical Nickel-Catalyzed C–H Arylation: Synthetic Scope and Mechanistic Investigations

[Image: see text] An iridium photocatalyst and visible light facilitate a room temperature, nickel-catalyzed coupling of (hetero)aryl bromides with activated α-heterosubstituted or benzylic C(sp(3))–H bonds. Mechanistic investigations on this unprecedented transformation have uncovered the possibili...

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Detalles Bibliográficos
Publicado en:J Am Chem Soc
Main Authors: Heitz, Drew R., Tellis, John C., Molander, Gary A.
Formato: Artigo
Idioma:Inglês
Publicado: American Chemical Society 2016
Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC5054938/
https://ncbi.nlm.nih.gov/pubmed/27653500
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b04789
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