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Nickel-Catalyzed Negishi Arylations of Propargylic Bromides: A Mechanistic Investigation
[Image: see text] Although nickel-catalyzed stereoconvergent couplings of racemic alkyl electrophiles are emerging as a powerful tool in organic chemistry, to date there have been no systematic mechanistic studies of such processes. Herein, we examine the pathway for enantioselective Negishi arylati...
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| Udgivet i: | J Am Chem Soc |
|---|---|
| Main Authors: | , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
American Chemical
Society
2014
|
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4277758/ https://ncbi.nlm.nih.gov/pubmed/25402209 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja508718m |
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