C−H Functionalization—Prediction of Selectivity in Iridium(I)‐Catalyzed Hydrogen Isotope Exchange Competition Reactions

An assessment of the C−H activation catalyst [(COD)Ir(IMes)(PPh(3))]PF(6) (COD=1,5‐cyclooctadiene, IMes=1,3‐bis(2,4,6‐trimethylphenyl)imidazol‐2‐ylidene) in the deuteration of phenyl rings containing different functional directing groups is divulged. Competition experiments have revealed a clear ord...

Descrizione completa

Salvato in:
Dettagli Bibliografici
Pubblicato in:Angew Chem Int Ed Engl
Autori principali: Valero, Mégane, Kruissink, Thomas, Blass, Jennifer, Weck, Remo, Güssregen, Stefan, Plowright, Alleyn T., Derdau, Volker
Natura: Artigo
Lingua:Inglês
Pubblicazione: John Wiley and Sons Inc. 2020
Soggetti:
Communications
Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC7232431/
https://ncbi.nlm.nih.gov/pubmed/31917506
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201914220
Tags: Aggiungi Tag
Nessun Tag, puoi essere il primo ad aggiungerne! !

Documenti analoghi