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Carbon Dioxide Activation at Metal Centers: Evolution of Charge Transfer from Mg (.+) to CO(2) in [MgCO(2)(H(2)O)(n)](.+), n=0–8
We investigate activation of carbon dioxide by singly charged hydrated magnesium cations Mg (.+)(H(2)O)(n), through infrared multiple photon dissociation (IRMPD) spectroscopy combined with quantum chemical calculations. The spectra of [MgCO(2)(H(2)O)(n)](.+) in the 1250–4000 cm(−1) region show a sha...
Shranjeno v:
| izdano v: | Angew Chem Int Ed Engl |
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| Main Authors: | , , , , |
| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
John Wiley and Sons Inc.
2020
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| Teme: | |
| Online dostop: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7217156/ https://ncbi.nlm.nih.gov/pubmed/32100953 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202001292 |
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