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Carbon Dioxide Activation at Metal Centers: Evolution of Charge Transfer from Mg (.+) to CO(2) in [MgCO(2)(H(2)O)(n)](.+), n=0–8

We investigate activation of carbon dioxide by singly charged hydrated magnesium cations Mg (.+)(H(2)O)(n), through infrared multiple photon dissociation (IRMPD) spectroscopy combined with quantum chemical calculations. The spectra of [MgCO(2)(H(2)O)(n)](.+) in the 1250–4000 cm(−1) region show a sha...

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Publicado en:Angew Chem Int Ed Engl
Main Authors: Barwa, Erik, Pascher, Tobias F., Ončák, Milan, van der Linde, Christian, Beyer, Martin K.
Formato: Artigo
Idioma:Inglês
Publicado: John Wiley and Sons Inc. 2020
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Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC7217156/
https://ncbi.nlm.nih.gov/pubmed/32100953
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202001292
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