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Electronic spectroscopy and nanocalorimetry of hydrated magnesium ions [Mg(H(2)O)(n)](+), n = 20–70: spontaneous formation of a hydrated electron?

Hydrated singly charged magnesium ions [Mg(H(2)O)(n)](+) are thought to consist of an Mg(2+) ion and a hydrated electron for n > 15. This idea is based on mass spectra, which exhibit a transition from [MgOH(H(2)O)(n–1)](+) to [Mg(H(2)O)(n)](+) around n = 15–22, black-body infrared radiative disso...

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Detalhes bibliográficos
Publicado no:Faraday Discuss
Main Authors: Taxer, Thomas, Ončák, Milan, Barwa, Erik, van der Linde, Christian, Beyer, Martin K.
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2019
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6677030/
https://ncbi.nlm.nih.gov/pubmed/30994636
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8fd00204e
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