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NHC-Ni catalyzed enantioselective synthesis of 1,4-dienes by cross-hydroalkenylation of cyclic 1,3-dienes and heterosubstituted terminal olefins

Enantioenriched 1,4-dienes are versatile building blocks in asymmetric synthesis, therefore their efficient synthesis directly from chemical feedstock is highly sought after. Here, we show an enantioselective cross-hydroalkenylation of cyclic 1,3-diene and hetero-substituted terminal olefin by using...

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Detalhes bibliográficos
Publicado no:Nat Commun
Main Authors: Chen, Yang, Dang, Liang, Ho, Chun-Yu
Formato: Artigo
Idioma:Inglês
Publicado em: Nature Publishing Group UK 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7210895/
https://ncbi.nlm.nih.gov/pubmed/32385240
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41467-020-16139-2
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