Anti-Markovnikov Hydroamination of Unactivated Alkenes with Primary Alkyl Amines

We report here a photocatalytic method for the intermolecular anti-Markovnikov hydroamination of unactivated olefins with primary alkyl amines to selectively furnish secondary amine products. These reactions proceed through aminium radical cation (ARC) intermediates and occur at room temperature und...

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Detaylı Bibliyografya
Yayımlandı:J Am Chem Soc
Asıl Yazarlar: Miller, David C., Ganley, Jacob M., Musacchio, Andrew J., Sherwood, Trevor C., Ewing, William R., Knowles, Robert R.
Materyal Türü: Artigo
Dil:Inglês
Baskı/Yayın Bilgisi: 2019
Konular:
Article
Online Erişim:https://ncbi.nlm.nih.gov/pmc/articles/PMC7202396/
https://ncbi.nlm.nih.gov/pubmed/31603324
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b08746
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