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Anti-Markovnikov Hydroamination of Unactivated Alkenes with Primary Alkyl Amines
We report here a photocatalytic method for the intermolecular anti-Markovnikov hydroamination of unactivated olefins with primary alkyl amines to selectively furnish secondary amine products. These reactions proceed through aminium radical cation (ARC) intermediates and occur at room temperature und...
Sparad:
| I publikationen: | J Am Chem Soc |
|---|---|
| Huvudupphovsmän: | , , , , , |
| Materialtyp: | Artigo |
| Språk: | Inglês |
| Publicerad: |
2019
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| Ämnen: | |
| Länkar: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7202396/ https://ncbi.nlm.nih.gov/pubmed/31603324 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b08746 |
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