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Anti-Markovnikov Hydroamination of Unactivated Alkenes with Primary Alkyl Amines
We report here a photocatalytic method for the intermolecular anti-Markovnikov hydroamination of unactivated olefins with primary alkyl amines to selectively furnish secondary amine products. These reactions proceed through aminium radical cation (ARC) intermediates and occur at room temperature und...
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| Publicado no: | J Am Chem Soc |
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| Main Authors: | , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2019
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7202396/ https://ncbi.nlm.nih.gov/pubmed/31603324 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b08746 |
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