Regio‐ and Stereoselective Synthesis of 1,1‐Diborylalkenes via Brønsted Base‐Catalyzed Mixed Diboration of Alkynyl Esters and Amides with BpinBdan

The NaOtBu‐catalyzed mixed 1,1‐diboration of terminal alkynes using the unsymmetrical diboron reagent BpinBdan (pin = pinacolato; dan = 1,8‐diaminonaphthalene) proceeds in a regio‐ and stereoselective fashion affording moderate to high yields of 1,1‐diborylalkenes bearing orthogonal boron protecting...

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Bibliografiske detaljer
Udgivet i:European J Org Chem
Main Authors: Liu, Xiaocui, Ming, Wenbo, Luo, Xiaoling, Friedrich, Alexandra, Maier, Jan, Radius, Udo, Santos, Webster L., Marder, Todd B.
Format: Artigo
Sprog:Inglês
Udgivet: John Wiley and Sons Inc. 2020
Fag:
Communications
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC7187442/
https://ncbi.nlm.nih.gov/pubmed/32362780
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/ejoc.202000128
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