A Structurally Characterized Cobalt(I) σ‐Alkane Complex

A cobalt σ‐alkane complex, [Co(Cy(2)P(CH(2))(4)PCy(2))(norbornane)][BAr(F) (4)], was synthesized by a single‐crystal to single‐crystal solid/gas hydrogenation from a norbornadiene precursor, and its structure was determined by X‐ray crystallography. Magnetic data show this complex to be a triplet. P...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Boyd, Timothy M., Tegner, Bengt E., Tizzard, Graham J., Martínez‐Martínez, Antonio J., Neale, Samuel E., Hayward, Michael A., Coles, Simon J., Macgregor, Stuart A., Weller, Andrew S.
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2020
Assuntos:
Communications
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7187152/
https://ncbi.nlm.nih.gov/pubmed/31943626
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201914940
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