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A Rhodium–Pentane Sigma‐Alkane Complex: Characterization in the Solid State by Experimental and Computational Techniques
The pentane σ‐complex [Rh{Cy(2)P(CH(2)CH(2))PCy(2)}(η(2):η(2)‐C(5)H(12))][BAr(F) (4)] is synthesized by a solid/gas single‐crystal to single‐crystal transformation by addition of H(2) to a precursor 1,3‐pentadiene complex. Characterization by low temperature single‐crystal X‐ray diffraction (150 K)...
Shranjeno v:
| izdano v: | Angew Chem Int Ed Engl |
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| Main Authors: | , , , , , |
| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
John Wiley and Sons Inc.
2016
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| Teme: | |
| Online dostop: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4797708/ https://ncbi.nlm.nih.gov/pubmed/26880330 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201511269 |
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