A Rhodium–Pentane Sigma‐Alkane Complex: Characterization in the Solid State by Experimental and Computational Techniques

The pentane σ‐complex [Rh{Cy(2)P(CH(2)CH(2))PCy(2)}(η(2):η(2)‐C(5)H(12))][BAr(F) (4)] is synthesized by a solid/gas single‐crystal to single‐crystal transformation by addition of H(2) to a precursor 1,3‐pentadiene complex. Characterization by low temperature single‐crystal X‐ray diffraction (150 K)...

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Bibliografske podrobnosti
izdano v:Angew Chem Int Ed Engl
Main Authors: Chadwick, F. Mark, Rees, Nicholas H., Weller, Andrew S., Krämer, Tobias, Iannuzzi, Marcella, Macgregor, Stuart A.
Format: Artigo
Jezik:Inglês
Izdano: John Wiley and Sons Inc. 2016
Teme:
Communications
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC4797708/
https://ncbi.nlm.nih.gov/pubmed/26880330
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201511269
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